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Barcelona suffered a shock 2-0 home defeat by Spanish Primera Liga newcomers Hercules on Saturday.
Paraguayan striker Nelson Valdez scored both goals at Nou Camp to hand the newly promoted side their first win of the season.
Esteban Vigo's men ended the Catalans' 16-month unbeaten home run.
Barca's arch-rivals Real Madrid registered a hard-fought 1-0 victory over Osasuna later on Saturday.
Summer signing Ricardo Carvalho scored the only goal of the game to give Jose Mourinho his first win with the capital club.
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